Difunctional ammonium ionic liquids with bicyclic cations

Anna Turguła , Katarzyna Materna , Daniela Gwiazdowska , Filip Walkiewicz , Katarzyna Marcinkowska , Juliusz Pernak

Abstract

The increasing limitations regarding the applied amounts of plant protection make hybrid ionic liquids an interesting class of compounds belonging to the III generation ILs. There are known examples of biologically active compounds in the literature, the structure of which is based on a monoalkyl derivative of 1,4-diazabicyclo[2.2.2]octane (DABCO). In the framework of the presented study, an efficient three-step method was developed for the synthesis of novel bicyclic herbicidal ionic liquids in which an alky derivative of DABCO was used as the cation and the 4-chloro-2-methylphenoxyacetic anion originated from a commonly applied herbicidal acid, MCPA. The synthesized new ILs were purified and identified and their surface activity, thermal stability and solubility were characterized. Furthermore, their herbicidal activity under greenhouse conditions towards common weed species present in agricultural crops and antimicrobial properties were also evaluated. The high biological activity of the synthesized ILs was correlated with their surface active properties. The obtained results confirmed the dual functionality of the synthesized herbicidal ionic liquids.
Author Anna Turguła - Politechnika Poznańska (PP)
Anna Turguła,,
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, Katarzyna Materna - Politechnika Poznańska
Katarzyna Materna,,
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, Daniela Gwiazdowska (WT / KPPJ)
Daniela Gwiazdowska,,
- Department of Natural Science and Quality Assurance
, Filip Walkiewicz - Politechnika Poznańska
Filip Walkiewicz,,
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, Katarzyna Marcinkowska
Katarzyna Marcinkowska,,
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, Juliusz Pernak - Politechnika Poznańska
Juliusz Pernak,,
-
Journal seriesNew Journal of Chemistry, ISSN 1144-0546, e-ISSN 1369-9261, (N/A 70 pkt)
Issue year2019
Vol43
No11
Pages4477-4488
Publication size in sheets0.55
Keywords in Polishciecze jonowe, aktywność biologiczna
Keywords in Englishliquid ionic, biological activity
ASJC Classification1503 Catalysis; 1600 General Chemistry; 2505 Materials Chemistry
DOIDOI:10.1039/C8NJ06054A
URL https://pubs.rsc.org/en/content/articlelanding/2019/nj/c8nj06054a#!divAbstract
Languageen angielski
Score (nominal)70
Score sourcejournalList
ScoreMinisterial score = 70.0, 14-04-2020, ArticleFromJournal
Publication indicators WoS Citations = 0; Scopus SNIP (Source Normalised Impact per Paper): 2016 = 0.766; WoS Impact Factor: 2018 = 3.069 (2) - 2018=3.038 (5)
Citation count*5 (2020-08-07)
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* presented citation count is obtained through Internet information analysis and it is close to the number calculated by the Publish or Perish system.
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